RID-TRAPPER . Immediately Dangerous to Life or Health Concentrations (IDLH) CAS number: 7637-07-2. �4�[(�R�=�@(�)U�����o������D@��A�TU���bȕi�PI��m����h Warfarin. H331 Toxic if inhaled. Boron Trichloride Solution Safety Data Sheet according to Regulation (EC) No. %PDF-1.6 %���� Brief Profile - Last updated: 29/01/2021 Print. 0000012937 00000 n 0000020822 00000 n 1977). Boron reacts with halogens to give the corresponding trihalides.Boron trichloride is, however, produced industrially by direct chlorination of boron oxide and carbon at 500 °C.. B 2 O 3 + 3 C + 3 Cl 2 → 2 BCl 3 + 3 CO. Boron trifluoride. Boron trifluoride etherate Revision Date 19-Jan-2018 General Advice Immediate medical attention is required. *��O%-(U9�%�v9K,A�� ���%�Bk=�@=�+������������B��? Each Documentation summarizes and evaluates the scientific data from which its TLV ® or BEI ® is derived. 1008 125. (EPA, 1998) Health Hazard. Boron Trichloride Solution Safety Data Sheet according to Regulation (EC) No. 0000038421 00000 n 3.5 TLV-STEL: Not listed. $48.00 Strong irritant to tissue. Click here to view press release.. 3640 Park 42 Drive | Cincinnati, Ohio 45241 | Tel: 513-742-2020, Web Design and Development by Matrix Group International, Inc. ® DOT ID & Guide. For Boron trifluoride, the BOD adopted the ACGIH TLV of 0.1 ppm (8-hour exposure limit), but maintained the existing exposure limit of 1 ppm (Ceiling Limit) as BC … The similarity in toxicity values for boron trifluoride and boron trichloride with the hydrolysis products tends to support limited hydrolysis. fBoron Tribromide is REACTIVE and a DANGEROUS EXPLOSION HAZARD. The ACGIH has also … Product Name: Boron trichloride MSDS# E-4566-I Date: Oct. 15, 2013 Boron trichloride Boron trichloride Boron chloride, Trichloroborane. Every boron trifluoride valve is equipped with a device consisting of a platinum disc in back of a plug containing a metal that will melt at approx 70 °C. Boron Trichloride BCl 3 Grade Semicon 4N5 ULSI 5N Gigabit 5N5 Purity, % 99.995 99.999 99.9995 Metals, ppbw Oxygen ≤9 ppmv ≤1.0 ppmv ≤0.5 ppmv Al ≤20 Ni ≤10 Nitrogen ≤30 ppmv ≤4.0 ppmv ≤0.5 ppmv Cr ≤10 Na ≤20 Boron Tribromide is a colorless, fuming liquid with a strong odor. It compiles information from several government agencies and organizations. trailer <<493820AEF0F64C44B7DD14502C981E2C>]>> startxref 0 %%EOF 51 0 obj <>stream 0000034480 00000 n Flash Point Nonflammable TLV 1 ppm Boiling Point 91.3°C @ 760mm Hg Freezing Point -46°C APPLICATIONS Liquid boron source used in p-type deposition processes Replaces diborane (B2H6) and boron trichloride (BCl3) BBr3 oxidizes at process temperatures to form B2O3. 0000016294 00000 n ACGIH® is pleased to announce new members for its 2021 Board of Directors and its 2021 Nominating Committee. Boron trichloride and aniline react violently in the absence of a coolant or diluent. Lab coat. May cause severe burns to skin. It compiles information from several government agencies and organizations. Exposure controls Appropriate engineering controls : Use corrosion-proof equipment. #��w�C��w&tص�@H���m�w���Rc �>�r�zZ�!�/y��J��~��5�t BORON TRICHLORIDE SYNONYMS: Trichloroborane 2. May 1994. Workplace Exposure Limits NIOSH: The recommended airborne exposure limit (REL) is 1 ppm, which should not be exceeded at any time. Formula. Gloves. It is also used in the refining of aluminium, magnesium, zinc, and copper alloys to remove nitrides, carbides, and oxides from molten metal. Vapor respirator. 0000001256 00000 n UN 1741 CHEMICAL NAME AND SYNONYMS Boron Trichloride, Boron Chloride, Trichloroborane DOT HAZARD CLASS Division 2.3 (Poison Gas) ISSUE DATE AND REVISIONS Revised March 2001 FORMULA BCl 3 HEALTH HAZARD DATA EMERGENCY OVERVIEW Boron Trichloride is a poisonous, corrosive, … The probit function has been derived according to the methodology described in RIVM report 2015 -0102. Boron trichloride n-Hexane 3-Methylpentane Hazard statements H225 Highly flammable liquid and vapor. 0000043971 00000 n 0000004082 00000 n 0000018135 00000 n Product Name: Boron trichloride MSDS# E-4566-F Date: 10/15/2004 Boron trichloride Boron trichloride Boron chloride, Trichloroborane. Prolonged exposure of the containers to fire or … ED2275000. Type of substance Composition: mono-constituent substance Origin: inorganic Total tonnage band Total range: 100 - 1 000 tonnes per annum REACH Registered as: FULL 0000038208 00000 n description Substance description Substance description. 0000009737 00000 n Exposure controls/personal protection Ingredient name Exposure limits Appropriate engineering controls:Use only with adequate ventilation. ���Y8���u���A���{��:��m?�$�i7��MKLnn�PO�f��a�b pm=�����a�0�%*�i���2�N'�6�6��JX���������)@��� u� endstream endobj 5 0 obj <> endobj 6 0 obj <>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC]/ExtGState<>>>/Type/Page>> endobj 7 0 obj <>stream 0000034117 00000 n Boron trichloride. s��֎A�9 �8kkפGS�!b�\��ڥ��\�\�%��H�N*sg����Ξ#m�r�� R���r�پ�ی�Sv��?yN�B���byd��Iǧ_��+;�r���e���>PO>|A��(�̜�%7��W��b ��|j�7���0'{�.\-��&x�r���[,��;���'�� ���BaX����'��� ��I{�m�l9�۰�[NÅ��#��T��/�u'Z;�2�Ch@�ɖ This Documentation is available for download in PDF format. 3. as inhalable particulate). �Pk�#�`U�|C˫�dk�svg�hcO���7mhY��,s�}rll� ��|�Q�J*��6�k�7}��+hazw��MgbP�]ʑ+�[��>���2�*X��/�TB���n~+N�����:������)^Ӄ>�`�* �;��զ�"/P��I�:YN{ ���Ǧ���\:�u hĵ0Őp�[�k`N�w����Ln��\��C�䱏�&M�r�6bA\j�1���pK��6�\K+�i#�Ѿg~�L��}cMT��b�ӯKZ�a2X�ꆸ��s�}g���V/]��j�/2 ��ʡ���$��UU�v"d\/00#��,��4T��͸#/����x@���k��B"�m�DCw5^��!X���a>/�A~����ĺ� ��*/���c�Qչ�VL��6 C�L�ɻ� H314 Causes severe skin burns and eye damage. 3), boron tribromide (TLV-Ceiling = 10 mg/m. Praxair recommends compliance with the OSHA and ACGIH (2000) limits of 5 ppm (ceiling) for hydrogen chloride, formed by the hydrolysis of boron trichloride. f Boron Tribromide may affect the nervous system. Gloves. Boron trichloride. Member - $48.00 NonMember - $60.00 Org Supporter - $0.00 Emergency Overview 3. Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) Boron trifluoride diethyletherate TWA: 0.1 ppm Ceiling: 0.7 ppm Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration Engineering Measures Use only under a chemical fume hood. C: 0.7 ppm Section 8. Use a local exhaust system, if necessary, to prevent oxygen Other Relevant Information. The 1-h LC 50 for boron trichloride in rats is 2,541 ppm (Vernot et al. 0000019172 00000 n UBE was the first company to produce boron trichloride in Japan, and it is of the highest quality and purity, making a perfect choice for a dry-etching gas for aluminum wires. Boron fluoride, Trifluoroborane CAS No. Be sure to use an approved/certified respirator or equivalent. 1270 ppm None currently established. Immediate medical attention is required. Org Supporter - 0000014694 00000 n Boron trichloride. Caution is advised. 1977). Formula. 0000001935 00000 n Description of Substance: Colorless gas with a pungent, suffocating odor. NO. It is highly reactive toward water. Gives off irritating or toxic fumes (or gases) in a fire. 1008 125. Calcium silicate, synthetic nonfibrous. Boron trifluoride. Current OSHA PEL: 1 ppm (3 mg/m3) CEILING. TLV-TWA (ACGIH) LD50 (Species & Routes) INGREDIENTS CAS NUMBER % (VOL) LC50 (Rat, 4 hrs.) Boron tribromide's vapor pressure ranges from approximately 15mm of Hg at 0 o C, 63mm of Hg at 25 o C to 170mm of Hg at 50 o C. Boron Trichloride - chemical formula BCl 3, boron trichloride is a corrosive toxic gas with a TLV of 5ppm. Boron Halides *Call … Boron trichloride . Molecular Weight: 117.17: UN Code: 1741: Permissible Concentration: TLV-TWA 0.5ppm 1.5mg/㎥ Description: Colorless Liquid: Odor: Choking Odor: Specific Gravity NOTE: Ceiling limits are not Time Weighted Average (TWA). 0000011171 00000 n This in turn reacts at silicon surface to form ele‐ 7637-07-2 RTECS No. Triorthocresyl phosphate. 0000019763 00000 n Show this safety data sheet to the doctor in attendance. THRESHOLD LIMIT VALUE: None currently established (ACGIH-2001). NIOSH REL: 1 ppm (3 mg/m3) CEILING. Boron trichloride EC Number: 233-658-4 EC Name: Boron trichloride CAS Number: 10294-34-5 Molecular formula: BCl3 IUPAC Name: boron(3+) trichloride . Oral, esophageal, and stomach burns are common. 0000018884 00000 n Atomic layer etch and pulsed plasma etch. Signs and Symptoms of Acute Boron Trichloride Exposure: Signs and symptoms of acute ingestion of boron trichloride may be severe and include salivation, intense thirst, difficulty in swallowing, chills, pain, and shock. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Date of issue: 21/03/2018 Revision date: : Version: 1.0 21/03/2018 EN (English US) 1/9 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. 0000034878 00000 n Hazards Identification Toxic, corrosive liquid and gas under pressure. However, it set a provisional guideline of 0.5 mg/L for boron in drinking water, based on a tolerable daily intake (TDI) of 0.16 mg/kg-day (WHO, 2003). 0000044471 00000 n 0000043759 00000 n H361 Suspected of damaging fertility or the unborn child. Boron Halides *Call emergency numbers 24 hours a day only for spills, leaks, fire, exposure, or accidents involving this product. Vapor respirator. 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